Fe-supported perlite applied for the degradation of Rhodamine B dye by Heterogeneous Fenton reaction
DOI:
https://doi.org/10.34024/jsse.2024.v2.19444Keywords:
Heterogeneous Fenton, Perlite, Rhodamine B, catalysisAbstract
This study aimed to evaluate a technique of Fe ion impregnation on perlite mineral and assess its behavior in a heterogeneous Fenton-like reaction, at room temperature and under acidic and alkaline conditions in the removal of Rhodamine B dye. For the catalyst preparation, a suspension of heptahydrated ferrous sulfate (FeSO4.7H2O) was used, followed by thermal treatment (calcination). Different doses of H2O2 (35% v/v) were applied to evaluate dye removal rates. Fe leaching in reaction media was analyzed. Rhodamine B removal at pH 4, 7, 9, 10, and 11 had the respective removal rates of 99.8%, 57.4%, 73.1%, 77.5%, and 96.9% in 240 minutes of reaction. At pH 12, there was 99.7% removal in 110 minutes of reaction. Reactions performed with low dosages of hydrogen peroxide showed, at pH 4 and 11, removal percentages of 95.8% and 90.2%, respectively, in 150 minutes of reaction. Under the same conditions, at pH 12, the removal percentage was 98.6% in 105 minutes. The synthesized catalyst exhibited satisfactory activity under acidic and alkaline conditions, for three cycles, showing promise for applications in heterogeneous Fenton reactions on a large scale.
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Accepted 2025-01-13
Published 2025-01-15
